@article{oai:repo.lib.tut.ac.jp:02000156, author = {山本, 一輝 and 小野, 湧貴 and 稲田, 亮史 and Yamamoto, Kazuki and Ono, Yuki and Inada, Ryoji}, issue = {9}, journal = {Heliyon}, month = {May}, note = {We investigated the reactivity of P2-type honeycomb layered oxides Na2Ni2TeO6 (NNTO) and Na2Zn2TeO6 (NZTO) co-fired at the temperature from 500 °C to 800 °C. From X-ray diffraction measurements, it was found that the reaction between NNTO and NZTO is unremarkable at the temperature below 700 °C. However, when annealed at 800 °C, they formed the solid-solution phase without any secondary phases. The NNTO and NZTO composite pellets co-fired at 800 °C showed sodium-ion conductivity well above 10−4 S cm−1 at room temperature, indicating that the solid-solution phase of NNTO and NZTO has good ionic conductivity. A maximum room temperature conductivity of 7.4 × 10−4 S cm−1 was confirmed at the mixing ratio NNTO: NZTO = 0.5 : 1.5. These results can be applied to the fabrication of all-solid-state batteries using NNTO as the cathode active material and NZTO as the solid electrolyte via a simple co-sintering process.}, title = {Characterization of co-fired sodium-ion conductive Na2Ni2TeO6 and Na2Zn2TeO6 with honeycomb layer structure}, volume = {10}, year = {2024} }