{"_buckets": {"deposit": "f9b630ce-b557-4f52-9524-a1a4f78e144b"}, "_deposit": {"created_by": 27, "id": "2049", "owners": [27], "pid": {"revision_id": 0, "type": "depid", "value": "2049"}, "status": "published"}, "_oai": {"id": "oai:repo.lib.tut.ac.jp:00002049", "sets": ["9"]}, "author_link": ["3857", "3023", "3862", "3861", "3858", "2977", "2978", "3859", "2973", "2982", "3020", "3860"], "item_10001_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-06-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageStart": "26", "bibliographicVolumeNumber": "4", "bibliographic_titles": [{"bibliographic_title": "Batteries"}, {"bibliographic_title": "Batteries", "bibliographic_titleLang": "en"}]}]}, "item_10001_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Garnet-type Li7-xLa3Zr2-xTaxO12 (LLZT) is considered a good candidate for the solid electrolyte in all-solid-state lithium batteries because of its reasonably high conductivity around 10-3 S cm-1 at room temperature and stability against lithium (Li) metal with the lowest redox potential. In this study, we synthesized LLZT with a tantalum (Ta) content of 0.45 via a conventional solid-state reaction process and constructed a Li/LLZT/Li symmetric cell by attaching Li metal foils on the polished top and bottom surfaces of an LLZT pellet. We investigated the influence of heating temperatures and times on the interfacial charge-transfer resistance between LLZT and the Li metal electrode. In addition, the effect of the interface resistance on the stability for Li deposition and dissolution was examined using a galvanostatic cycling test. The lowest interfacial resistance of 25 ohm cm2 at room temperature was obtained by heating at 175 degree \u000eCelsius (5 degree \u000eCelsius lower than the melting point of Li) for three to five hours. We confirmed that the current density at which the short circuit occurs in the Li/LLZT/Li cell via the propagation of Li dendrite into LLZT increases with decreasing interfacial charge transfer resistance.", "subitem_description_type": "Abstract"}]}, "item_10001_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "MDPI"}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.3390/batteries4020026", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "関連サイト", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "MDPIサイト"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.mdpi.com/2313-0105/4/2/26", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution"}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2313-0105", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "稲田, 亮史"}], "nameIdentifiers": [{"nameIdentifier": "2973", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000030345954", "nameIdentifierScheme": "NRID"}, {"nameIdentifier": "30345954", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30345954"}]}, {"creatorNames": [{"creatorName": "保田, 哲志"}], "nameIdentifiers": [{"nameIdentifier": "3857", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "細川, 寛将"}], "nameIdentifiers": [{"nameIdentifier": "3858", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "斎藤, 正也"}], "nameIdentifiers": [{"nameIdentifier": "3859", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "東城, 友都"}], "nameIdentifiers": [{"nameIdentifier": "3020", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30736385", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30736385"}]}, {"creatorNames": [{"creatorName": "櫻井, 庸司"}], "nameIdentifiers": [{"nameIdentifier": "2977", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000080452217", "nameIdentifierScheme": "NRID"}, {"nameIdentifier": "80452217", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80452217"}]}, {"creatorNames": [{"creatorName": "Inada, Ryoji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "2978", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasuda, Satoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3860", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hosokawa, Hiromasa", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3861", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saito, Masaya", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3862", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tojo, Tomohiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3023", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakurai, Yoji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "2982", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "b23130105-0004-26.pdf", "filesize": [{"value": "5.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_6", "mimetype": "application/pdf", "size": 5300000.0, "url": {"label": "b23130105-0004-26.pdf", "url": "https://repo.lib.tut.ac.jp/record/2049/files/b23130105-0004-26.pdf"}, "version_id": "04431a88-5690-4e1f-aa8e-bc2fed670e21"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "garnet", "subitem_subject_scheme": "Other"}, {"subitem_subject": "solid electrolyte", "subitem_subject_scheme": "Other"}, {"subitem_subject": "lithium metal", "subitem_subject_scheme": "Other"}, {"subitem_subject": "interface", "subitem_subject_scheme": "Other"}, {"subitem_subject": "charge-transfer resistance", "subitem_subject_scheme": "Other"}, {"subitem_subject": "garnet", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "solid electrolyte", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "lithium metal", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "interface", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "charge-transfer resistance", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Formation and Stability of Interface between Garnet-Type Ta-doped Li7La3Zr2O12 Solid Electrolyte and Lithium Metal Electrode", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Formation and Stability of Interface between Garnet-Type Ta-doped Li7La3Zr2O12 Solid Electrolyte and Lithium Metal Electrode"}, {"subitem_title": "Formation and Stability of Interface between Garnet-Type Ta-doped Li7La3Zr2O12 Solid Electrolyte and Lithium Metal Electrode", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "27", "path": ["9"], "permalink_uri": "https://repo.lib.tut.ac.jp/records/2049", "pubdate": {"attribute_name": "公開日", "attribute_value": "2018-06-07"}, "publish_date": "2018-06-07", "publish_status": "0", "recid": "2049", "relation": {}, "relation_version_is_last": true, "title": ["Formation and Stability of Interface between Garnet-Type Ta-doped Li7La3Zr2O12 Solid Electrolyte and Lithium Metal Electrode"], "weko_shared_id": -1}