{"_buckets": {"deposit": "13d9d050-4979-4ecf-95be-a9ac1b31ac65"}, "_deposit": {"created_by": 27, "id": "2052", "owners": [27], "pid": {"revision_id": 0, "type": "depid", "value": "2052"}, "status": "published"}, "_oai": {"id": "oai:repo.lib.tut.ac.jp:00002052", "sets": ["9"]}, "author_link": ["3814", "3023", "2977", "2978", "2982", "2973", "3811", "3020", "3870", "3869"], "item_10001_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "A5162", "bibliographicPageStart": "A5157", "bibliographicVolumeNumber": "166", "bibliographic_titles": [{"bibliographic_title": "Jornal of The Elctrochemical Society "}, {"bibliographic_title": "Jornal of The Elctrochemical Society ", "bibliographic_titleLang": "en"}]}]}, "item_10001_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "In this study, we evaluate the electrochemical properties of TiNb2O7 (TNO) single particle using a particle-current collector integrated microelectrode, in which TNO single particle with the size of approximately 10 μm was bonded on the tip of a tungsten microelectrode by platinum deposition using a focused ion beam process unit (FIB). Cyclic voltammogram of TNO single particle showed the reversible redox peaks at around 1.6−1.7 V vs. Li/Li+. Anodic peak current is higher than cathodic one at a fixed scan rate, indicating faster reaction during Li+ extraction (i.e. discharge) than Li+ insertion (i.e. charge) of TNO particle. This tendency was also confirmed in C-rate dependence of charge and discharge capacities. From the results for galvanostatic intermittent titration testing (GITT), we confirmed that at the equilibrium potential vs. Li/Li+ below 1.5 V, apparent chemical diffusion coefficient of Li+ in TNO at Li+ extraction process is much larger than at Li+ insertion process. Furthermore, the capacity retention of TNO single particle tested at current of 10C after 2000 cycles was above 99%, indicating excellent intrinsic stability of TNO single particle for Li+ insertion and extraction reaction. ", "subitem_description_type": "Abstract"}]}, "item_10001_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Electrochemical Society "}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1149/2.0241903jes", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "関連サイト", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "The Electrochemical Society"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://jes.ecsdl.org/content/166/3/A5157.full", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© The Author(s) 2018. Published by ECS.This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. "}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0013-4651", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "稲田, 亮史"}], "nameIdentifiers": [{"nameIdentifier": "2973", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000030345954", "nameIdentifierScheme": "NRID"}, {"nameIdentifier": "30345954", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30345954"}]}, {"creatorNames": [{"creatorName": "熊坂, 玲衣"}], "nameIdentifiers": [{"nameIdentifier": "3811", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "稻邊, 秀斗"}], "nameIdentifiers": [{"nameIdentifier": "3869", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "東城, 友都"}], "nameIdentifiers": [{"nameIdentifier": "3020", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30736385", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30736385"}]}, {"creatorNames": [{"creatorName": "櫻井, 庸司"}], "nameIdentifiers": [{"nameIdentifier": "2977", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000080452217", "nameIdentifierScheme": "NRID"}, {"nameIdentifier": "80452217", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80452217"}]}, {"creatorNames": [{"creatorName": "Inada, Ryoji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "2978", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kumasaka, Rei", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3814", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Inabe, Shuto", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3870", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tojo, Tomohiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "3023", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakurai, Yoji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "2982", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-12-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "j00134651-0166-a5157.pdf", "filesize": [{"value": "1.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_6", "mimetype": "application/pdf", "size": 1200000.0, "url": {"label": "j00134651-0166-a5157.pdf", "url": "https://repo.lib.tut.ac.jp/record/2052/files/j00134651-0166-a5157.pdf"}, "version_id": "577995cc-bf37-45fd-aa76-cf1d2a58e6bd"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Batteries-Lithium", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Anode material", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Lithium-ion battery", "subitem_subject_scheme": "Other"}, {"subitem_subject": "TiNb2O7", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Batteries-Lithium", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Anode material", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Lithium-ion battery", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "TiNb2O7", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Li+ Insertion/Extraction Properties for TiNb2O7 Single Particle Characterized by a Particle-Current Collector Integrated Microelectrode", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Li+ Insertion/Extraction Properties for TiNb2O7 Single Particle Characterized by a Particle-Current Collector Integrated Microelectrode"}, {"subitem_title": "Li+ Insertion/Extraction Properties for TiNb2O7 Single Particle Characterized by a Particle-Current Collector Integrated Microelectrode", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "27", "path": ["9"], "permalink_uri": "https://repo.lib.tut.ac.jp/records/2052", "pubdate": {"attribute_name": "公開日", "attribute_value": "2018-12-07"}, "publish_date": "2018-12-07", "publish_status": "0", "recid": "2052", "relation": {}, "relation_version_is_last": true, "title": ["Li+ Insertion/Extraction Properties for TiNb2O7 Single Particle Characterized by a Particle-Current Collector Integrated Microelectrode"], "weko_shared_id": -1}