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  1. 学術雑誌論文

Tolerance for Li dendrite penetration in Ta-doped Li7La3Zr2O12 solid electrolytes sintered with Li2.3C0.7B0.3O3 additive

https://repo.lib.tut.ac.jp/records/2158
https://repo.lib.tut.ac.jp/records/2158
cf12f2b0-2f58-4579-9d82-9b22e3e6c639
名前 / ファイル ライセンス アクション
m0167577X-0279-128481.pdf m0167577X-0279-128481.pdf (987.1 kB)
license.icon
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-08-18
タイトル
タイトル Tolerance for Li dendrite penetration in Ta-doped Li7La3Zr2O12 solid electrolytes sintered with Li2.3C0.7B0.3O3 additive
タイトル
言語 en
タイトル Tolerance for Li dendrite penetration in Ta-doped Li7La3Zr2O12 solid electrolytes sintered with Li2.3C0.7B0.3O3 additive
言語
言語 eng
資源タイプ
資源タイプ journal article
著者 細川, 寛将

× 細川, 寛将

WEKO 3980

細川, 寛将

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竹田, 惇人

× 竹田, 惇人

WEKO 3981

竹田, 惇人

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稲田, 亮史

× 稲田, 亮史

WEKO 2973
NRID 1000030345954
e-Rad 30345954

稲田, 亮史

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櫻井, 庸司

× 櫻井, 庸司

WEKO 2977
NRID 1000080452217
e-Rad 80452217

櫻井, 庸司

Search repository
Hosokawa, Hiromasa

× Hosokawa, Hiromasa

WEKO 3861

en Hosokawa, Hiromasa

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Takeda, Atsuto

× Takeda, Atsuto

WEKO 3982

en Takeda, Atsuto

Search repository
Inada, Ryoji

× Inada, Ryoji

WEKO 2978

en Inada, Ryoji

Search repository
Sakurai, Yoji

× Sakurai, Yoji

WEKO 2982

en Sakurai, Yoji

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抄録
内容記述タイプ Abstract
内容記述 We fabricated garnet-type Ta-doped Li7La3Zr2O12 (LLZTO) / Li2.3C0.7B0.3O3 (LCBO) composite ceramic solid electrolytes. By adding the appropriate amount of LCBO to LLZTO, composite solid electrolytes were densified by sintering at 1000ºC without covering the pellet with LLZTO mother powder. LLZTO/LCBO Composites with LCBO volume contents of 20 and 50% showed the ionic conductivity well above 1 x 10-4 S cm-1 at room temperature. Li plating and stripping property for LLZTO/LCBO composites was evaluated using symmetric cells with Li metal electrodes at room temperature. As results, a symmetric cell composed of composite solid electrolyte with low LCBO volume content was stably cycled at the current density up to 0.3 mA cm-2, but increasing the amount of LCBO significantly lowered the current density where the Li dendrite penetration in solid electrolyte occurs. This indicates that LCBO addition is effective for lowering the sintering temperature of LLZTO but the smaller LCBO content is prefer to maintain the tolerance for Li dendrite penetration at high current density.
書誌情報 Materials Letters
en : Materials Letters

巻 279, p. 128481, 発行日 2020
出版者
出版者 Elsevier
ISSN
収録物識別子タイプ ISSN
収録物識別子 0167-577X
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 10.1016/j.matlet.2020.128481
権利
権利情報 Embargo 24month, Licence CC BY-NC-ND
関連サイト
識別子タイプ URI
関連識別子 https://www.sciencedirect.com/science/article/pii/S0167577X20311873
関連名称 Elsevierサイト
著者版フラグ
出版タイプ AM
キーワード
主題 solid electrolyte
キーワード
主題 garnet
キーワード
主題 composite
キーワード
主題 ionic conductivity
キーワード
主題 Li dendrite
キーワード
主題 solid electrolyte
キーワード
主題 garnet
キーワード
主題 composite
キーワード
主題 ionic conductivity
キーワード
主題 Li dendrite
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