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  1. 学術雑誌論文

Effect of Postannealing on the Properties of a Ta-Doped Li7La3Zr2O12 Solid Electrolyte Degraded by Li Dendrite Penetration

https://repo.lib.tut.ac.jp/records/2171
https://repo.lib.tut.ac.jp/records/2171
6ef571e0-dd0f-45a8-8696-ec8663f38fa7
名前 / ファイル ライセンス アクション
A25740962-0003-12517.pdf A25740962-0003-12517.pdf (4.9 MB)
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Item type 学術雑誌論文 / Journal Article(1)
公開日 2021-01-26
タイトル
タイトル Effect of Postannealing on the Properties of a Ta-Doped Li7La3Zr2O12 Solid Electrolyte Degraded by Li Dendrite Penetration
タイトル
言語 en
タイトル Effect of Postannealing on the Properties of a Ta-Doped Li7La3Zr2O12 Solid Electrolyte Degraded by Li Dendrite Penetration
言語
言語 eng
資源タイプ
資源タイプ journal article
著者 稲田, 亮史

× 稲田, 亮史

WEKO 2973
NRID 1000030345954
e-Rad 30345954

稲田, 亮史

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竹田, 惇人

× 竹田, 惇人

WEKO 3981

竹田, 惇人

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山崎, 佑輔

× 山崎, 佑輔

WEKO 3996

山崎, 佑輔

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三宅, 翔太郎

× 三宅, 翔太郎

WEKO 3997

三宅, 翔太郎

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櫻井, 庸司

× 櫻井, 庸司

WEKO 2977
NRID 1000080452217
e-Rad 80452217

櫻井, 庸司

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Thangadurai, Venkataraman

× Thangadurai, Venkataraman

WEKO 3998

Thangadurai, Venkataraman

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Inada, Ryoji

× Inada, Ryoji

WEKO 2978

en Inada, Ryoji

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Takeda, Atsuto

× Takeda, Atsuto

WEKO 3982

en Takeda, Atsuto

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Yamazaki, Yusuke

× Yamazaki, Yusuke

WEKO 3999

en Yamazaki, Yusuke

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Miyake, Shotaro

× Miyake, Shotaro

WEKO 4000

en Miyake, Shotaro

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Sakurai, Yoji

× Sakurai, Yoji

WEKO 2982

en Sakurai, Yoji

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Venkataraman, Thangadurai

× Venkataraman, Thangadurai

WEKO 4001

en Venkataraman, Thangadurai

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抄録
内容記述タイプ Abstract
内容記述 In this study, we investigated the effect of postannealing on the properties of a garnet-type Ta-doped Li6.55La3Zr1.55Ta0.45O12 (Ta-LLZO) ceramic solid electrolyte degraded by lithium (Li) dendrite penetration during electrochemical Li plating and stripping testing in a Li/Ta-LLZO/Li symmetric cell. After the electrochemical testing in the symmetric cell, the Ta-LLZO pellet was taken out of the cell and then annealed at 800 or 900 °C for 4 h in air. It was confirmed that locally discolored spots on the Ta-LLZO surface at which Li dendrite penetrated disappeared after postannealing. The total conductivity of the annealed Ta-LLZO pellet was lower than the initial one but was retained above 10–4 S cm–1 at room temperature. When the soft-shorted or degraded area size by Li dendrite penetration is localized and smaller than the area size for Ta-LLZO, it is expected that the degradation of the conductivity of annealed Ta-LLZO becomes smaller. Obtained electrochemical results indicate the possibility of reusing the degraded garnet-type solid electrolyte by Li dendrite penetration in another all-solid-state Li battery.
書誌情報 ACS Applied Energy Materials
en : ACS Applied Energy Materials

巻 3, 号 12, p. 12517-12524, 発行日 2020
出版者
出版者 American Chemical Society
ISSN
収録物識別子タイプ ISSN
収録物識別子 2574-0962
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 10.1021/acsaem.0c02474
権利
権利情報 Copyright © 2020 American Chemical Society , Embargo 12 Months
関連サイト
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acsaem.0c02474
関連名称 ACSサイト
著者版フラグ
出版タイプ AM
キーワード
主題 solid electrolyte
キーワード
主題 garnet
キーワード
主題 ionic conductivity
キーワード
主題 Li dendrite
キーワード
主題 postannealing
キーワード
主題 solid electrolyte
キーワード
主題 garnet
キーワード
主題 ionic conductivity
キーワード
主題 Li dendrite
キーワード
主題 postannealing
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