Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2022-10-13 |
タイトル |
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タイトル |
Characterization of Sn4P3 film formed by aerosol deposition for lithium-ion battery anode with liquid electrolyte and solid polymer electrolyte |
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言語 |
en |
言語 |
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言語 |
eng |
資源タイプ |
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資源タイプ |
journal article |
アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
著者 |
東, 大貴
稲田, 亮史
Azuma, Daiki
Inada, Ryoji
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抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
We fabricated Sn4P3 thin films by aerosol deposition process. Sn4P3 powder pulverized by a ball milling was used as raw material and splayed onto a glass or a stainless steel substrate to form the film via impact consolidation. Electrochemical property as a lithium-ion battery anode was characterized using both organic liquid electrolyte and poly (ethylene oxide) based solid polymer electrolyte. The initial reversible capacities in both a liquid-type and a solid-polymer cells with a lithium metal as a counter electrode attained to approximately 900 mAh g − 1, while the capacity retention of Sn4P3 film electrode after galvanostatic cycling in a cell with a polymer electrolyte was much better than in a cell with a liquid electrolyte. It was also found that the microstructural change of the film after galvanostatic cycling in polymer-type cell is significantly suppressed compared to the film in a liquid-type cell. These results suggest that high-capacity alloy-based anode shows better electrochemical performance in solid-state batteries with deformable solid electrolyte. |
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言語 |
en |
bibliographic_information |
en : Thin Solid Films
巻 761,
p. 139537,
発行日 2022-10-11
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出版者 |
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出版者 |
Elsevier |
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言語 |
en |
item_10001_source_id_9 |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
1879-2731 |
item_10001_relation_14 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
10.1016/j.tsf.2022.139537 |
権利 |
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権利情報 |
Accepted Version Embargo:24 months, Licence:CC BY-NC-ND |
関連サイト |
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識別子タイプ |
URI |
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関連識別子 |
https://www.sciencedirect.com/science/article/pii/S0040609022004400 |
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関連名称 |
Elsevier Webサイト |
出版タイプ |
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出版タイプ |
AM |
キーワード |
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主題 |
Tin phosphide |
キーワード |
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主題 |
Thin film |
キーワード |
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主題 |
Aerosol deposition |
キーワード |
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主題 |
Polymer electrolyte |
キーワード |
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主題 |
Lithium ion battery anode |
キーワード |
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主題 |
Tin phosphide |
キーワード |
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主題 |
Thin film |
キーワード |
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主題 |
Aerosol deposition |
キーワード |
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主題 |
Polymer electrolyte |
キーワード |
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主題 |
Lithium ion battery anode |