| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2019-07-22 |
| タイトル |
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タイトル |
Characterization of Sn4P3–Carbon Composite Films for Lithium-Ion Battery Anode Fabricated by Aerosol Deposition |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ |
journal article |
| 著者 |
森高, 冬毅
山下, 優
東城, 友都
稲田, 亮史
櫻井, 庸司
Moritaka, Toki
Yamashita, Yuh
Tojo, Tomohiro
Inada, Ryoji
Sakurai, Yoji
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
We fabricated tin phosphide–carbon (Sn4P3/C) composite film by aerosol deposition (AD) and investigated its electrochemical performance for a lithium-ion battery anode. Sn4P3/C composite powders prepared by a ball milling was used as raw material and deposited onto a stainless steel substrate to form the composite film via impact consolidation. The Sn4P3/C composite film fabricated by AD showed much better electrochemical performance than the Sn4P3 film without complexing carbon. Although both films showed initial discharge (Li+ extraction) capacities of approximately 1000 mAh g-1, Sn4P3/C films retained higher reversible capacity above 700 mAh g-1 after 100 cycles of charge and discharge processes while the capacity of Sn4P3 film rapidly degraded with cycling. In addition, by controlling the potential window in galvanostatic testing, Sn4P3/C composite film retained the reversible capacity of 380 mAh g-1 even after 400 cycles. The complexed carbon works not only as a buer to suppress the collapse of electrodes by large volume change of Sn4P3 in charge and discharge reactions but also as an electronic conduction path among the atomized active material particles in the film. |
| bibliographic_information |
Nanomaterials
en : Nanomaterials
巻 9,
号 7,
p. 1032,
発行日 2019
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| 出版者 |
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出版者 |
MDPI |
| item_10001_source_id_9 |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2079-4991 |
| item_10001_relation_14 |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
DOI |
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関連識別子 |
10.3390/nano9071032 |
| 権利 |
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権利情報 |
(c)2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license. |
| 関連サイト |
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識別子タイプ |
URI |
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関連識別子 |
https://www.mdpi.com/2079-4991/9/7/1032 |
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関連名称 |
MDPIサイト |
| 出版タイプ |
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出版タイプ |
VoR |
| キーワード |
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主題 |
tin phosphide |
| キーワード |
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主題 |
carbon |
| キーワード |
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主題 |
composite film |
| キーワード |
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主題 |
aerosol deposition |
| キーワード |
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|
主題 |
lithium-ion battery |
| キーワード |
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|
主題 |
anode |
| キーワード |
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|
主題 |
tin phosphide |
| キーワード |
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|
主題 |
carbon |
| キーワード |
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|
主題 |
composite film |
| キーワード |
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|
主題 |
aerosol deposition |
| キーワード |
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|
主題 |
lithium-ion battery |
| キーワード |
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主題 |
anode |
n20794991-0009-1032.pdf (6.8 MB)
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